N,N′-Bis[2-(methoxycarbonyl)ethyl]ethane-1,2-diammonium dichloride

نویسندگان

  • Goran N. Kaluderović
  • Anchan Paethanom
  • Christoph Wagner
  • Tibor J. Sabo
  • Harry Schmidt
چکیده

In the crystal structure of the title compound, C(10)H(22)N(2)O(4) (2+)·2Cl(-) or (H(2)Me(2)eddp)Cl(2) (H(2)Me(2)eddp(2+) is the dimethyl N,N'-di-3-propane-carboxylato-ethane-1,2-diyldiimin-ium cation), the packing is stabilized by an infinite two-dimensional ⋯Cl⋯H-N-H⋯Cl⋯ hydrogen-bonding network. In addition, short C-H⋯Cl contacts are observed.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

N,N′-Bis(2-hydroxy­ethyl)-N,N′-[ethyl­ene­dioxy­bis(o-phenyl­enemethyl­ene)]­diammonium fumarate tetra­hydrate

The reaction of 1,2-bis-{2-[(2-hydroxy-ethyl)amino-methyl]-phen-oxy}ethane and fumaric acid in a mixed solution in ethanol-water (1:1 v/v) yields the title compound, C(20)H(30)N(2)O(4) (2+)·C(4)H(2)O(4) (2-)·4H(2)O. In the crystal structure, the anions, cations and water mol-ecules are connected via O-H⋯O and N-H⋯O hydrogen bonds into a three-dimensional network. The fumarate anion and the N,N'...

متن کامل

1,2-Bis[(pyridin-2-ylmethyl)sulfanyl]ethane and its dimorphic hydrochloride salt.

Although having been described as a liquid in the literature for 41 years, 1,2-bis[(pyridin-2-ylmethyl)sulfanyl]ethane, C(14)H(16)N(2)S(2), (I), has now been obtained as monoclinic crystals via a new and convenient method of purification. Molecules of (I) are located on crystallographic inversion centres and are held together by C-H···N and C-H···S interactions, resulting in the formation of a ...

متن کامل

{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ4 N,N′,N′′,N′′′}(thio­cyanato-κN)zinc(II) perchlorate

In the title compound, [Zn(NCS)(C(16)H(18)N(4))]ClO(4), the Zn(II) atom is five-coordinated by four N atoms of the Schiff base ligand N,N'-bis-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine in the basal plane, and by the N atom of a thio-cyanate ligand at the apical position, forming a distorted square-pyramidal geometry. The r.m.s. deviation from a plane through the four N atoms of the Schiff b...

متن کامل

{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ4 N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II)

A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetra-dentate Schiff base, N,N'-bis-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine. The copper centre assumes a tetra-gonally distorted pseudo-octa-hedral geometry with the O atoms of two trifluoro-methane-sulfonate anions coordinated weakly in the axial positions. The Cu-N distances l...

متن کامل

Ethane-1,2-diammonium dibromide: a redetermination at 100 K

In the redetermined [for the previous study, see Søtofte (1976 ▶). Acta Chem. Scand. Ser. A, 30, 309-311] crystal structure of the title compound, C(2)H(10)N(2) (2+)·2Br(-), the H atoms have been located and the hydrogen-bonding scheme is described. The ethane-1,2-diammonium cation lies over a crystallographic inversion centre and straddles a crystallographic mirror plane with the C and N atoms...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008